When you perform a search like [site:nameofthewebsite.it], Google shows the resources of the website in no specific order. If it’s true that, generally, on top of the list you will find the homepage, it’s not true that the other resources are listed in order of importance.
Many years ago it was possible to use a hack to see all the resources from the search engine in order of PageRank, but this function was eliminated by Google a long time ago.